二茂铁衍生物及三阶非线性光学活性化合物的合成、结构及其功能性质研究

安徽大学硕士学位论文AbstractBased on the detailed investigation of a great deal of related literature,the historyand current researchs on macrocycle chemistry ferrocene ramification werereviewd.A new metal organic compound and a series of complexes were synthesizedandelectrochemistry property were studied.In this thesis,series of organiccompounds had been designed and synthesized and photochemistry property had alsobeen studied.In this thesis,we had done some useful work in order to get some newmaterial with light and electricity functionality.The mail achievements in my work is summarized as follows:1.In the first part,a new metal organic compound and a series of complexes weresynthesized.They were characterized by element analysis,IR,UV,Mass Spectra,molar conductance and cyclic voltammetry.The ligand was characterized bycrystal structure determination.We also discussed the relationship with thestructure and properties.At the same time,We made three new modified carbonpaste electrodes incorporated with Lo,HLSM,HLSB and determinated the tracemetal with them.2.In the second part,series of organic compounds with fluorenone,malononittrile andD--A molecular structure had been designed and synthesized.They werecharacterized by element analysis,IR,UV,HNMR.Fluorescent spectra andthird-order nonlinear optics property studies on them were given in this part.Sixcompounds of them were characterized by crystal structure determination.Wealso discussed the relationship with the structure and properties.The result of ourwork by now shows that nine compounds of them exhibit third-order nonlinearoptics activity.Keywords:macrocycle complex,ferrocene,modified carbon paste electrodeorganic compound,third-order nonlinear optics